IADR Abstract Archives

Elastic moduli of resin-composites with silorane, ormocer and dimethacrylate matrices

Objective: To determine the elastic properties of a silorane- and an experimental ormocer- versus dimethacrylate-based matrix composites. Methods: Two materials of novel matrix chemistry: Filtek Silorane (SIL) and experimental Ormocer (ORM) were compared with two dimethacrylate composites: Grandio (GRA) and ELS - Ceramco (ELS). Cylindrical specimens (5 mm diameter x 6 mm) were prepared in moulds from each material (n=12) by thorough irradiation and stored dry for 24 h. Six specimens were used to measure the Young's modulus (E), allowing free radial expansion under axial-compressive loading at 1mm/min. The other six specimens were radially constricted in a rigid stainless steel ring during compression, from which the bulk modulus (B) was calculated using equations of elasticity. Poisson's ratio (ν) was calculated from the equation ν = 0.5 - (E/6B). The results were submitted to One-way ANOVA (p=0.05). To determine any correlation between elastic moduli and w/w filler content, Pearson's test was applied. Results: The filler content, E, B and ν values are reported in the Table below. Statistically significant differences were found among the materials. A significant correlation was observed between elastic moduli and filler content (r2=0.99). Thus materials with higher filler content, i.e: ORM and GRA, presented higher elastic moduli than SIL and ELS.

Material

SIL

ORM

GRA

ELS

Filler content (% w/w)

76

86

87

74

E (GPa)

4.0 (0.7) B

7.2 (0.7) A

7.9 (0.5) A

3.1 (0.3) B

B (GPa)

14.6 (0.9) C

23.6 (0.9) A

23.1 (1.2) A

16.9 (0.8) B

Poisson's ratio - ν

0.45

0.45

0.44

0.47

Conclusions: Elastic moduli varied linearly with filler-fraction, being maximal for the ormocer and the conventional dimethacrylate. The silorane composite and the ‘ELS' dimethacrylate had lower moduli. These lower moduli may contribute to reduced shrinkage-stress.


Division: Pan European Federation Meeting
Meeting: 2008 Pan European Federation Meeting (London, England)
Location: London, England
Year: 2008
Final Presentation ID: 186
Abstract Category|Abstract Category(s): PEF IADR 2008
Authors
  • Cavalcante, Larissa Maria  ( The University of Manchester, Manchester, N/A, United Kingdom )
  • Schneider, Luis Felipe  ( The University of Manchester, Manchester, N/A, United Kingdom )
  • Masouras, Konstantinos  ( The University of Manchester, Manchester, N/A, United Kingdom )
  • Silikas, N.  ( The University of Manchester, Manchester, N/A, United Kingdom )
  • Watts, David  ( The University of Manchester, Manchester, N/A, United Kingdom )
  • SESSION INFORMATION
    Poster Session
    Materials Properties
    09/10/2008