IADR Abstract Archives

Degree of conversion of a fiber-reinforced composite measured by micro-Raman

Objective: To evaluate the depth of cure and curing profile of a new fiber-reinforced composite when applied in bulk.

Methods:

Three cylinder-shaped composite blocks (diameter: 8 mm, thickness: 10 mm) were prepared using the fiber-reinforced composite EverX Posterior (‘EX-P’, GC), the bulk-fill composite SDR (‘SDR’, Dentsply) and the conventional micro-hybrid composite Filtek Z100 (‘Z100’, 3M ESPE). The top surface of each block was compressed by a slide glass, and light-cured using a polywave LED unit (Bluephase 20i, Ivoclar Vivadent) at 1200 mW/cm2 for 20s. After 24-hour storage (37°C), the blocks were cut in half and the degree of conversion (DC) was mapped using micro-Raman spectroscopy (Senterra, Bruker), with DC calculated as the ratio of peak intensities of the aliphatic 1640 cm-1 and aromatic 1610 cm-1 peaks in cured and uncured materials. The depth effect and distance relative to the specimen center were statistically analyzed using a linear mixed-effects model.

Results:

Mean degree of conversion (%; ±SD) at the different depths (mm).

0-1

1-2

2-3

3-4

4-5

5-6

6-7

7-8

8-9

9-10

EX-P

80±2

80±3

79±3

78±2

77±3

76±3

74±3

72±3

70±4

68±5

SDR

79±2

79±2

79±2

79±2

78±2

78±2

77±3

76±2

74±3

72±3

Z100

74±3

74±3

72±4

69±4

65±5

61±6

46±10

31±9

 

 

Maximum DC of Z100 was significantly lower (p=0.0011) than that of both bulk-fill composites. In contrast to DC of both bulk-fill composites, DC of the conventional composite decreased more rapidly (p<0.001). Statistics revealed a homogenous DC for both bulk-fill composites, while for the conventional composite DC at the cylinder bottom was up to 10% lower at the periphery than at the center.

Conclusion: The fiber-reinforced composite polymerized homogenously up to at least 6-mm depth; up to 10-mm depth DC only decreased with 15% as compared to maximum DC.

Division: Continental European Division Meeting
Meeting: 2013 Continental European Division Meeting (Florence, Italy)
Location: Florence, Italy
Year: 2013
Final Presentation ID: 535
Abstract Category|Abstract Category(s): Scientific Groups
Authors
  • Li, Xin  ( KU Leuven (University of Leuven) & Dentistry, University Hospitals Leuven, Leuven, N/A, Belgium )
  • Pongprueksa, Pong  ( KU Leuven (University of Leuven) & Dentistry, University Hospitals Leuven, Leuven, N/A, Belgium )
  • De Munck, Jan  ( KU Leuven BIOMAT, Department of Oral Health Sciences, KU Leuven (University of Leuven) & Dentistry, University Hospitals Leuven, Belgium, Leuven, , Belgium )
  • Van Meerbeek, Bart  ( KU Leuven (University of Leuven) & Dentistry, University Hospitals Leuven, Leuven, N/A, Belgium )
  • SESSION INFORMATION
    Poster Session
    Dental Materials - Resin I
    09/07/2013