Methods : Three groups of Co-Cr dental alloy specimens (VI-COMP/Dentsply, Elephant Dental, Okta-C/Sae Dental Products Inc. and ST2725G/SINT-TECH n:4) were prepared employing casting, milling and SLM and were then veneered with a dental porcelain (GC Initial MC, GC). In two specimens per group a bonding agent (GC Initial INmetalbonder) was applied prior to porcelain veneering. After metallographic preparation the metal-ceramic interfaces were examined by SEM/EDX (BE imaging and line scan elemental analysis across the interface).
Results : BE imaging revealed continuous interfaces in all specimens. Line scan analysis showed a Cr-rich zone at the interface of alloys directly veneered with porcelain. Such a zone was missing from the alloys treated with the bonding agent. This finding may be explained by the higher chemical affinity of O with elements of the bonding agent (i.e. Ti).
Conclusion : All interfaces tested were continuous. The use of the bonding-agent reduced the interfacial Cr content. This may influence the interfacial concentration of the adherent metal oxides and consequently the metal-ceramic bond strength.