IADR Abstract Archives

Influence of Photo-activation Method on Mechanical Properties of Experimental Composites

Objective: This study evaluated the influence of different methods of photo-activation on degree of conversion (DC), flexural strength (FS) and flexural modulus (FM) of composites prepared with different proportions of glass and ceramic filler particles.

Materials and Methods: A blend of BisGMA, BisEMA, UDMA and TEGDMA was prepared with the camphorquinone-amine photo-initiator system. A total of 60wt% of silanized filler particles was added. The filler particles used were: Ba-Al-Si with 0.5µm and/or SiO2 with 0.04µm. From this composition, four types of composites with differences in the relationship between filler particles were prepared. A ratio in % of Ba-Al-Si and SiO2, respectively, were: G1-100/0, G2-90/10, G3-80/20 and G4-70/30. During the preparation of the samples, three polymerization methods were used: CL–ContinuousLight, SS–SoftStart and PD–PulseDelay. FreeLight2LED unit was used for photo-activation. Samples (n=10) with 7.0x2.0x1.0mm (length x width x height) were made and the DC was analyzed using Fourier transform infrared spectroscopy (FTIR).The same samples (n=10) were subjected to FS and FM using an universal testing machine (Instron) with a crosshead speed of 0.5mm/min.  ANOVA and Tukey test were performed.

Results: There was no statistical interaction for the values of DC (p=0.067).  For FS in MPa, CL produced the highest values in G1 (151.2) followed by SS (123.8) and PD (69.1). For all other groups there was no difference between CL and SS and PD showed the lowest values. Considering each photo-activation method separately, G1 showed the lowest values overall. For FM in GPa, G4 showed lowest values (4.7) in SS, while CL showed no difference in all groups.

Conclusions: The modulated methods, mainly PD, produced the lowest values of FS and FM. Composites with different filler ratios did not show different FM when photo-activated with CL, but the composite G3 usually showed the higher mechanical properties.

Division: IADR/LAR General Session
Meeting: 2012 IADR/LAR General Session (Iguaçu Falls, Brazil)
Location: Iguaçu Falls, Brazil
Year: 2012
Final Presentation ID: 724
Abstract Category|Abstract Category(s): Dental Materials 6: Polymer-based Materials-Chemistry and Composition
Authors
  • Machado-santos, Luciana  ( University of Taubate, Taubaté, N/A, Brazil )
  • Souza-junior, Eduardo José  ( Piracicaba Dental School, Piracicaba, N/A, Brazil )
  • Neves, Ana Christina Claro  ( University of Taubate, Taubaté, N/A, Brazil )
  • Silva-concilio, Lais Regiane  ( University of Taubate, Taubaté, N/A, Brazil )
  • Brandt, William Cunha  ( University of Taubate, Taubaté, N/A, Brazil )
  • SESSION INFORMATION
    Poster Session
    Photopolymerization and New Approaches to Dental Resins and Composites
    06/21/2012