IADR Abstract Archives

Degree of conversion of resin-luting agent containing different photoinitiator systems

Objective: The study analyzed the effect of the different photoinitiator systems (with two and three components) in the degree of conversion (DC) of experimental resin luting agents. 

Method: Resin luting agents containing BisGMA and TEGDMA and 65wt% of silaneted filler particles were prepared with the use of the photoinitiators: CQ-Camphoroquinone, PPD-Phenil Propanodione, BAPO-Bisacylphosphine Oxide, DMAEMA-Dimethylaminoethyl Methacrylate and DPIHFP-Diphenyliodonium Hexafluorphosphate. The combination used were: G1-CQ/DMAEMA, G2-CQ/DMAEMA/DPIHFP, G3-PPD/DMAEMA, G4- PPD/DMAEMA/DPIHFP, G5-BAPO/DMAEMA and G6- BAPO/DMAEMA/DPIHFP. The light curing unit used was a LED (BluePhase-Ivoclar). A power meter and a spectrometer (USB 2000) were used for show the total irradiance and the emitted in certain wavelengths. The curve of absorption of the photoinitiators was checked by a spectrometer (Varian Cary 5G). The luting material was photoactivated for 40 s through ceramic disk (Empress E-Max with 1 mm thick). Analysis of DC was made in FTIR. The data were submitted to the ANOVA and the Tukey`s test (5%). 

Result: In agreement with the results of DC (%) G5 (59.7) = G6 (59.5%) > G2 (49.2) > G4 (41.6) = G1 (41.2) > G3 (31.1). 

Conclusion: The photoinitiator BAPO produced the higher DC values and the ternary photoinitiator system produced higher DC values that binary photoinitiator system.

Division: IADR/LAR General Session
Meeting: 2012 IADR/LAR General Session (Iguaçu Falls, Brazil)
Location: Iguaçu Falls, Brazil
Year: 2012
Final Presentation ID: 723
Abstract Category|Abstract Category(s): Dental Materials 6: Polymer-based Materials-Chemistry and Composition
Authors
  • Brandt, William  ( Universidade de Taubate, Taubate, N/A, Brazil )
  • Silveira, Leonardo  ( Universidade de Taubate, Taubate, N/A, Brazil )
  • Souza-junior, Eduardo José  ( Piracicaba Dental School, Piracicaba, N/A, Brazil )
  • Silva-concilio, Lais  ( Universidade de Taubate, Taubate, N/A, Brazil )
  • Neves, Ana Christina  ( Universidade de Taubate, Taubaté / SP, N/A, Brazil )
  • Sinhoreti, Mário Alexandre  ( Piracicaba Dental School/State University of Campinas, Piracicaba, N/A, Brazil )
  • SESSION INFORMATION
    Poster Session
    Photopolymerization and New Approaches to Dental Resins and Composites
    06/21/2012