IADR Abstract Archives

Hygroscopic Expansion Kinetics of Resin-Modified Glass-Ionomer Cements

Objectives: 1) to measure the Linear Hygroscopic Expansion (LHE) of three RMGI cements: an experimental cement (EXP, Kerr), Rely X Luting (RXL, 3M), and Fuji Plus (FJP, GC America), along with a resin cement: Nexus 2 (NEX2, Kerr); and 2) to model the kinetics of LHE process. Methods: Specimens (n=3) were prepared using a ring mold (f/h: 30/3mm). The distance between two known points was measured using a measuring microscope initially and then at pre-determined time intervals (up to 90 days) after the specimens were stored in de-ionized water at 37 ° C. Non-linear regression analyses were performed on LHE as a function of time. Results: ANOVA analysis revealed that NEX2 resin cement had significantly lower LHE (p < 0.05) than all RMGI's. Among RMGI's, EXP had significantly lower LHE (p < 0.05) than RXL and FJP. The LHE process can be best described by the sum of a short-term and long-term first order processes: Et=EI{1-exp(-KI* t)} + EII{1-exp(-KII* t)}; where E and K are the equilibrium LHE and rate constant for each process. The half-life for each process was calculated as T=ln2/K.

Measured 90-day LHE, %

Parameters From Model

EI, %

TI, days

EII, %

TII, days

E¥ (=E1+EII), %

NEX2

0.36±0.05a

0.09

1.56

0.31

30.9

0.40

EXP

0.63±0.02b

0.55

0.48

0.09

10.3

0.64

RXL

1.12±0.02c

0.65

0.46

0.49

16.7

1.14

FJP

1.59±0.04d

0.83

0.59

0.76

12.1

1.59

*Means with the same letter are not statistically different at p < 0.05.

Conclusions:. The kinetics of the LHE can be modeled by the sum of a short-term first order process with a half-life of 0.46-1.56 days and a long-term first order process with a half-life of 10.3-30.9 days. NEX2 resin cement had a half-life that is much longer than those for RMGI's due to its hydrophobic resin matrix that slows down water absorption process.


Division: IADR/AADR/CADR General Session
Meeting: 2002 IADR/AADR/CADR General Session (San Diego, California)
Location: San Diego, California
Year: 2002
Final Presentation ID: 413
Abstract Category|Abstract Category(s): Dental Materials: III - Ceramics and Cements
Authors
  • Qian, Xuejun  ( Kerr Corporation, Orange, CA, USA )
  • Shellard, E.  ( Kerr Corporation, Orange, CA, USA )
  • SESSION INFORMATION
    Poster Session
    Cements, Surface Treatment, Luting, Opacity
    03/07/2002