IADR Abstract Archives

New Self-adhesive Resin Cement With Alkaline pH

Objectives: Current self-adhesive resin cements contain acidic monomers for promoting adhesion. They are acidic and have low polymerization degree of conversion. The new self-adhesive resin cement has an alkaline pH. The purpose of this study is to measure shear bond strength and degree of conversion of the new alkaline self-adhesive resin cement.
Methods: The pH of the new self-adhesive resin cement (TheraCem, Bisco) was tested on a moist pH Test Strip. Shear bond strength (n=5) on zirconia was tested using the ultradent jig method. The self-adhesive resin cement was placed on sandblasted zirconia surface through the ultradent jig mold (bonding area 4.5mm2). The cements were self-cured (15 min/37°C), stored in de-ionized water (37°C/24hours), and tested by Instron tester (crosshead-speed 1mm/min). Degree of conversion of self-adhesive cements was measured by FTIR-ATR up to 30 min at 25°C in dark. The data were analyzed statistically by one-way ANOVA and Student-t Tests.
Results: Results are shown in Table 1 and Table 2.
Conclusions: The new self-adhesive resin cement, TheraCem, has an alkaline pH after polymerization. It has a high bond strength to Zirconia and high degree of conversion.
IADR/AADR/CADR General Session
2017 IADR/AADR/CADR General Session (San Francisco, California)
San Francisco, California
2017
0286
Dental Materials 4: Adhesion
  • Chen, Liang  ( BISCO, Inc. , Schaumburg , Illinois , United States )
  • Gleave, Christine  ( BISCO, Inc. , Schaumburg , Illinois , United States )
  • Suh, Byoung  ( BISCO, Inc. , Schaumburg , Illinois , United States )
  • The authors are Bisco employees.
    Oral Session
    Dental Materials: Adhesion IV
    Wednesday, 03/22/2017 , 01:30PM - 03:00PM
    pH of TheraCem
    TimepH
    Right after mixing4
    5 minutes after mixing8 (already polymerized)
    10 minutes after mixing9 (already polymerized)
    30 minutes after mixing10 (already polymerized)

    Shear bond strength in MPa and degree of conversion (standard deviation).
    SubstratesProduct TypeShear bond strength (MPa, n=5)Degree of Conversion (%, n=3)
    TheraCEM (Bisco)Alkaline Self-adhesive 26.8(8.9) a68.0(1.5) a
    UniCem 2 (3M)Acidic Self-adhesive 16.7(6.2) ab34.3(7.1) e
    MaxCem E (Kerr)Acidic Self-adhesive 14.8(7.3) b55.1(1.9) c
    Calibra U (Dentsply)Acidic Self-adhesive 13.4(6.5) b48.8(1.4) d
    NX3 (Kerr) Neutral non-self-adhesive (amine-free)n.a61.8(0.7) b
    Duolink (Bisco)Neutral non-self-adhesive n.a66.8(1.5) a
    Means with different letters in the same column are statistically different (p<0.05)